Chlorido[4-chloro-2-(pyridin-2-ylmethyliminomethyl)phenolato-κ3 N,N′,O]copper(II)
نویسندگان
چکیده
In the title complex, [Cu(C(13)H(10)ClN(2)O)Cl], the Cu(II) ion is coordinated by one O atom and two N atoms of the tridentate Schiff base ligand and one chloride ion, forming a slightly distorted square-planar geometry. Weak Cu⋯Cl inter-actions [2.793 (5) Å] result in the formation of a chain along the a axis.
منابع مشابه
Chlorido{4-chloro-2-[(2-morpholinoethyl)iminomethyl]phenolato-κ3 N,N′,O}copper(II)
The Cu(II) atom in the title compound, [Cu(C(13)H(16)ClN(2)O(2))Cl], exists in a distorted square-planar coordination environment as the deprotonated Schiff base chelates to the Cu(II) atom through three atom sites. In the crystal structure, adjacent mol-ecules are linked by a Cu⋯Cl [3.011 (1) Å] bridge, generating a linear chain running along the b axis of the ortho-rhom-bic unit cell.
متن کاملN,N′,N′′ versus N,N′,O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear CuII compounds
It is demonstrated here that tridentate imine ligands can control the nuclearity of copper(II) complexes based on the donor atoms present in the ligand. The N,N',N''-donating imine ligand led to a mononuclear compound, namely di-chlorido-[N,N-dimethyl-N'-(pyridin-2-yl-methyl-idene)ethane-1,2-di-amine]copper(II) monohydrate, [CuCl2(C10H15N3)]·H2O, 1, while the N,N',O-donating imine ligand produc...
متن کامل{2-Bromo-4-chloro-6-[2-(diethylamino)ethyliminomethyl]phenolato-κ3 N,N′,O}(thiocyanato-κN)copper(II)
In the title compound, [Cu(C(13)H(17)BrClN(2)O)(NCS)], the Cu atom is in a slightly distorted square-planar geometry, coordinated by the three donor atoms of the ligand and the N atom of the isothio-cyanate group.
متن کامل(Azido-κN){(E)-2-[1-(pyridin-2-yl)ethylideneamino]phenolato-κ3 N,N′,O}copper(II)
In the title complex, [Cu(C13H11N2O)(N3)], the Cu(II) cation is four-coordinated by an N2O donor set of the tridentate Schiff base ligand and by the terminal N atom of the azide anion, forming a slightly distorted square-planar configuration.
متن کاملChlorido(2-{1-[(2-morpholinoethyl)imino]ethyl}phenolato-κ3 N,N′,O)copper(II)
In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H⋯Cl and C-H⋯O inter-actions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined cryst...
متن کامل